Porous Fe2O3 nanorod-decorated hollow carbon nanofibers for high-rate lithium storage

نویسندگان

چکیده

Abstract Transition metal oxides (TMOs) are considered as promising anode materials for lithium-ion batteries in comparison with conventional graphite anode. However, TMO anodes suffer severe volume expansion during charge/discharge process. In this respect, a porous Fe 2 O 3 nanorod-decorated hollow carbon nanofiber (HNF) is designed via combined electrospinning and hydrothermal method followed by proper annealing. FeOOH/PAN was prepared precursors sacrificial templates, @carbon (HNF-450) composite formed at 450 °C air. As batteries, HNF-450 exhibits outstanding rate performance cycling stability reversible discharge capacity of 1398 mAh g −1 after 100 cycles current density mA . Specific capacities 1682, 1515, 1293, 987, 687 achieved multiple densities 200, 300, 500, 1000, 2000 , respectively. When coupled commercial LiCoO cathode, the full cell delivered an initial 614/437 different densities. The improved electrochemical mainly attributed to free space provided unique structure, which effectively alleviates facilitates exposure more active sites lithiation/delithiation Graphical abstract Porous nanofibers exhibit high capacity.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Micro-sized porous carbon spheres with ultra-high rate capability for lithium storage.

Biomass-derived carbon materials, as one type of promising anode material for lithium ion batteries (LIBs), have demonstrated intrinsic potential and superiority. Here, we report a facile and efficient approach to fabricate micro-sized porous carbon spheres (PCSs) by an integrated procedure of enzymolysis, pre-oxidation, and carbonization. Benefiting from the uniquely abundant pore accessiblity...

متن کامل

Novel hollow α-Fe2O3 nanofibers via electrospinning for dye adsorption

Nanomaterials such as iron oxides and ferrites have been intensively investigated for water treatment and environmental remediation applications. In this work, hollow α-Fe2O3 nanofibers made of rice-like nanorods were successfully synthesized via a simple hydrothermal reaction on polyvinyl alcohol (PVA) nanofiber template followed by calcination. The crystallographic structure and the morpholog...

متن کامل

High interfacial lithium storage capability of hollow porous Mn2O3 nanostructures obtained from carbonate precursors.

The preparation of porous Mn2O3 boxes has been developed via a carbonate precursor route. As a Li-ion battery anode, it delivers a high reversible capacity of 1442 mA h g(-1) over 600 cycles at 800 mA g(-1), and 65% of the capacity originates from the gradually emerging interfacial storage contribution.

متن کامل

A unique hollow Li3VO4/carbon nanotube composite anode for high rate long-life lithium-ion batteries.

A unique hollow Li3VO4/CNT composite is synthesized via a facile method as an anode material in lithium batteries. Our work opens up the way for a promising material with high rate capability and good cycling stability due to its efficient Li(+) diffusion and relatively high structure stability.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Advanced composites and hybrid materials

سال: 2021

ISSN: ['2522-0128', '2522-0136']

DOI: https://doi.org/10.1007/s42114-021-00397-9